Chemistry News - May 2009 Archives
Fox Chase researchers first to determine structure in a class of self-regulating proteins
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At the MBL in Woods Hole, scientists discovered that cells use a very simple phase transition -- similar to water vapor condensing into dew -- to assemble and localize subcellular structures that are involved in formation of the embryo.
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Chrome has been used to add a protective coating and shiny luster to a wide range of metal products. But those features come at a heavy cost. The industrial process to create chrome is dangerous for workers and pollutes the environment. Now MIT researchers have developed a new nickel-tungsten alloy that is not only safer than chrome but also more durable.
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Scientists at Queen's University have discovered a new eco-friendly way of dissolving wood that may help its transformation into popular products such as biofuels, textiles, clothes and paper.
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One-step process derives raw material for fuels and plastic from plants rather than crude oil
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 | A new type of air-fueled battery could give up to ten times the energy storage of designs currently available.This step-change in capacity could pave the way for a new generation of electric cars, mobile phones and laptops. ...> Full Article |
Discovery is expected to lead to biochemistry textbook changes and new approaches to protein-engineered biofuels
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A new sponge-like material that is black, brittle and freeze-dried can pull off some pretty impressive feats. Designed by Northwestern University chemists, it can remove mercury from polluted water, easily separate hydrogen from other gases and is a more effective catalyst than the one currently used to pull sulfur out of crude oil. In fact, the material, a type of chalcogel, is twice as active as the conventional catalyst used in hydrodesulfurization.
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 | By creating a model of the active site found in a naturally occurring enzyme, chemists at the University of Illinois have described a catalyst that acts like nature's most pervasive hydrogen processor. ...> Full Article |
The inexpensive plastic now used to manufacture CDs and DVDs may soon be put to use in improving the integrity of electronics in aircraft, computers and iPhones. Thanks to a pair of grants from the US Air Force, a team of UH researchers have demonstrated ultra-high electrical conductive properties in these plastics. The findings are chronicled in a recent issue of the Journal of Applied Physics.
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 | Researchers at the University of Gothenburg, Sweden, have developed a new method to study single cells while exposing them to controlled environmental changes. The unique method, where a set of laser tweezers move the cell around in a microscopic channel system, allows the researchers to study how single cells react to stress induced by a constantly changing environment. ...> Full Article |
More efficient than commercial catalysts
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A URI chemistry professor's discovery of a new salt has been received with enthusiasm by companies seeking to develop an advanced lithium ion battery for use in the next generation of hybrid and electric vehicles.
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A hydrogen-rich compound discovered by Stanford researchers may help overcome one of the biggest hurdles to using hydrogen for fuel -- namely, how do you stuff enough hydrogen into a volume small enough to be practical for powering a car? The newly discovered material is a form of ammonia borane. Working at high pressure in an atmosphere artificially enriched with hydrogen, the scientists were able to ratchet up the hydrogen content by roughly 50 percent.
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New process for obtaining alkanes from bio-oil
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 | A large, international collaboration between Arizona State University, the University of California San Diego and the University of British Columbia, has come up with a surprising twist to photosynthesis by swapping a key metal necessary for turning sunlight into chemical energy. ...> Full Article |
A study lead by UC Merced's Elliott Campbell suggests that biomass used to generate electricity could be more efficient than ethanol. In the study, researchers found that biomass converted into electricity produced 81 percent more transportation miles and 108 percent more emissions offsets than ethanol.
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 | Thousands of small electric scooters, bicycles and wheelchairs throughout Europe and Asia are powered by LifePO4 -- a material used in advanced lithium-ion batteries developed by Universite de Montreal researchers. ...> Full Article |
In the world of small things, shape, order and orientation are surprisingly important, according to findings from a new study by chemists at Washington University in St. Louis. Lev Gelb, Washington University associate professor of chemistry, his graduate student Brian Barnes, and postdoctoral researcher Daniel Siderius, used computer simulations to study a very simple model of molecules on surfaces, which looks a lot like the computer game "Tetris."
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 | An international science team has determined the structure of chlorophyll molecules in green bacteria, which are super-efficient at harvesting light energy. Because the interactions that lead to the assembly of the chlorophyll molecules are rather simple, so they provide good models for designing artificial systems. The research one day could be used to build artificial photosynthetic systems, such as those that convert solar energy to electrical energy. ...> Full Article |
 | Parachute cords, climbing ropes, and smart coatings for bridges that change color when overstressed are several possible uses for force-sensitive polymers being developed by researchers at the University of Illinois. ...> Full Article |
In chemistry as well as in all adjoining sciences, an understanding of chemical bonding is of fundamental importance. Researchers of Ludwig-Maximilians-Universitaet Muenchen have now been able to detect the shortest single bond ever observed between atoms of chlorine and carbon in a molecule and to clarify the cause of the tight bond.
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