Chemistry News - January 2009 Archives
An ETH Zurich researcher has developed a computational method for predicting the structure of materials. He used it to solve the structure of a newly synthesized form of pure boron that displays some unusual physical properties and brings a surprise: it is partially ionic.
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A novel technology for synthesizing chemicals from plant material could produce liquid fuel for just over €0.50 a liter ($2.49 a gallon), say German scientists. But only if the infrastructure is set up in the right way, states the research published in this month's issue of Biofuels, Bioproducts & Biorefining.
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The enzyme DFPase is able to rapidly and efficiently detoxify chemical warfare agents such as Sarin, which was used in the Tokyo subway attacks in 1995. A detailed understanding of the mechanism by which the enzyme catalyzes chemical reactions is necessary for efforts aiming to improve its properties as a decontaminant. Its structure, which is closely related to its function, has now been determined by neutron diffraction.
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A team of scientists at the US Department of Energy's Brookhaven National Laboratory, in collaboration with researchers from the University of Delaware and Yeshiva University, has developed a new catalyst that could make ethanol-powered fuel cells feasible. The highly efficient catalyst performs two crucial, and previously unreachable steps needed to oxidize ethanol and produce clean energy in fuel cell reactions. Their results are published online in the Jan. 25, 2009 edition of Nature Materials.
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Engineers at the University of Liverpool have tested a new form of concrete designed to reduce the impact of bomb blasts in public areas.
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 | Scientists have discovered a way to produce hydrogen by exposing selected clusters of aluminum atoms to water. The findings are important because they demonstrate that it is the geometries of these aluminum clusters, rather than solely their electronic properties, that govern the proximity of the clusters' exposed active sites. The proximity of the clusters' exposed sites plays an important role in affecting the clusters' reactions with water. ...> Full Article |
 | A patented Michigan State University process to pre-treat corn-crop waste before conversion into ethanol means extra nutrients don't have to be added, cutting the cost of making biofuels from cellulose. The pretreatment process, developed by Bruce Dale, University Distinguished Professor of chemical engineering and materials science, uses ammonia to make the breakdown of cellulose and hemicellulose in plants 75 percent more efficient than when conventional enzymes alone are used. ...> Full Article |
 | Chalk crystallizes differently from the way we once thought it did. This discovery will allow the development of new scale inhibitors and other materials, and has also consequences for climate change. ...> Full Article |
 | Engineers and food scientists are teaming up to develop a new type of gelled fuel the consistency of orange marmalade designed to improve the safety, performance and range of rockets for space and military applications. ...> Full Article |
The creation of a reproducible crystallization process is a fundamental challenge to drug manufacturers, but a technique which provides real time detailed analyses of chemical processes could provide an answer.
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Water and energy are two resources on which modern society depends. As demands for these increase, researchers look to alternative technologies that promise both sustainability and reduced environmental impact. Engineered osmosis holds a key to addressing both the global need for affordable clean water and inexpensive sustainable energy according to Yale researchers.
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Algae is a livid green giveaway of nutrient pollution in a lake. Scientists would love to reproduce that action in tiny particles that would turn different colors if exposed to biological weapons, food spoilage or signs of poor health in the blood.
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Inexpensive solar cells, vastly improved medical imaging techniques and lighter more flexible television screens are among the potential applications envisioned for organic electronics. Recent experiments at University of Toronto may bring these closer thanks to new insights into ways molecules absorb and move energy.
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 | While exploring the properties of polymer formation a team of scientists at NIST made a fundamental discovery about these materials that could improve methods of creating the stable crystalline films that are widely used in electronics applications -- and also offer insight into a range of other phenomena. ...> Full Article |
University of Oklahoma researchers believe newer, more environmentally friendly fuels produced from biomass could create alternative energy solutions and alleviate dependence on foreign oil without requiring changes to current fuel infrastructure systems. According to Lance Lobban, director of the School of Chemical, Biological and Materials Engineering, the development of "green" fuels is an important part of the world's, and Oklahoma's, energy future.
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Using two simultaneous light-based probing techniques at the US Department of Energy's Brookhaven National Laboratory, a team of researchers has illuminated important details about a class of enzymes involved in everything from photosynthesis to the regulation of biological clocks.
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As a chemical for industrial processes, butanol is used in everything from brake fluid, to paint thinners, to plastics. According to a University of Illinois researcher, butanol made from plant material could displace butanol made from petroleum, just not at the fuel pump.
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 | Deuterated pyridine adopts a different crystalline form: a useful effect for pharmaceuticals? ...> Full Article |
A team of Baylor University researchers who have identified a variety of low-cost products that can be manufactured from coconuts in poor coastal regions have now developed a way to use coconut husks in automotive interiors.
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MIT engineers have developed a new, highly efficient way to pair up cells so they can be fused together into a hybrid cell. The new technique should make it much easier for scientists to study what happens when two cells are combined. For example, fusing an adult cell and an embryonic stem cell allows researchers to study the genetic reprogramming that occurs in such hybrids.
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